Review paper
Coordination chemistry of carboxamide ‘Nx’ ligands to metal ions for bio-inspired catalysis
Abstract
Deprotonated carboxamidate ‘N’ donors have been extensively explored as ligands to support metal ions with unusual higher oxidation states. Their ability to serve as both σ and π-electron donor, being resistant to oxidation and provide exceptional hydrolytic stability to a coordinated metal ion has altogether enhanced the broad applicability of carboxamidate ligands in bio-mimetic catalysis. Although the biological precedents with such class of...
Paper Details
Title
Coordination chemistry of carboxamide ‘Nx’ ligands to metal ions for bio-inspired catalysis
Published Date
Aug 1, 2020
Volume
417
Pages
213314 - 213314
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