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Coordination Chemistry Reviews
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#1Xiang-Yang Zhang (NU: Nanjing University)
#2Yu-Shun Yang (NU: Nanjing University)H-Index: 13
Last. Hai-Liang Zhu (NU: Nanjing University)H-Index: 38
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Abstract Being a widely used raw material in the manufacture of synthetic catalysts, agricultural chemicals and pharmaceutical products, hydrazine (N2H4) caused irreversible pollution to air, water and soil in our environment owing to its high toxic impact and massive use. In addition, during the metabolism process of certain drugs, such as isoniazid (INH), hydrazine can also be released, causing serious harm to human body. It has been proved by previous researches that hydrazine could cause sev...
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#1Mário S. Reis (Federal Fluminense University)H-Index: 17
Abstract Solid state refrigeration is a viable alternative for the conventional gas-compression technology due to the environmental friendliness of its materials, energy efficiency, and low noise. Research in this field is focused on the development of advanced prototypes and smart materials. This Review focuses on a special family of quantum materials: metal complexes. We introduce the fundamentals of caloric effects and magnetism of these complexes, discussing their applications at different r...
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#1Xuechao Cai (Zhengzhou University)H-Index: 1
#2Zhongxi Xie (Zhengzhou University)
Last. Hai-Long Jiang (USTC: University of Science and Technology of China)H-Index: 61
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Abstract Recently, nanoscale metal-organic frameworks (nanoMOFs), which leads to the discovery of a variety of properties not observed in their bulk counterparts, have attracted tremendous attention. To be specific, while possessing the properties of bulk MOF materials including high surface area, structural diversity and tailorability etc., nanoMOFs also have some unique advantages, such as accelerated adsorption/desorption kinetics and accessibility to the internal active sites. Moreover, due ...
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#1Olga P. Ajsuvakova (Yaroslavl State University)H-Index: 1
#2Alexey A. Tinkov (Yaroslavl State University)H-Index: 15
Last. Ioan Sarac (UASD: University of Agricultural Sciences, Dharwad)H-Index: 1
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Abstract The present study addresses existing data on the affinity and conjugation of sulfhydryl (thiol; -SH) groups of low- and high-molecular-weight biological ligands with mercury (Hg). The consequences of these interactions with special emphasis on pathways of Hg toxicity are highlighted. Cysteine (Cys) is considered the primary target of Hg, and link its sensitivity with thiol groups and cellular damage. In vivo, Hg complexes play a key role in Hg metabolism. Due to the increased affinity o...
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#1Sujata Kashyap (IITR: Indian Institute of Technology Roorkee)H-Index: 6
#2Ritesh Kumar SinghH-Index: 9
Last. Udai P. Singh (IITR: Indian Institute of Technology Roorkee)H-Index: 18
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Abstract Anion sensing is one of the most important aspects of chemistry and interest towards anion sensing, directly or indirectly, is evident from publications of the last two decades. Anion sensing is an induced response in a receptor in terms of an optical change (color change, UV–Vis and fluorescence) or an electrochemical change due to the recognition of one or more anions. A variety of ligands, including amides, urea, crown ethers etc., have been utilized from time to time as a sensor for...
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#1Uttara Basu (Braunschweig University of Technology)
#1Uttara BasuH-Index: 9
Last. Akhil R. ChakravartyH-Index: 53
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Abstract The discovery of cisplatin followed by its success in anticancer therapy laid the foundation of metal-based drug design and development. Further research led to discovery of other platinum containing complexes, namely, carboplatin and oxaliplatin. The disadvantages of the platinum-based drugs are their untoward side effects and drug resistance. This paved way for new metal-based anticancer drugs with a prospect for iron-based anticancer agents. Initial interest on the anticancer activit...
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#1Chakadola Panda (IISc: Indian Institute of Science)
#2Aniruddha Sarkar (IISc: Indian Institute of Science)
Last. Sayam Sen Gupta (IISc: Indian Institute of Science)H-Index: 21
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Abstract Deprotonated carboxamidate ‘N’ donors have been extensively explored as ligands to support metal ions with unusual higher oxidation states. Their ability to serve as both σ and π-electron donor, being resistant to oxidation and provide exceptional hydrolytic stability to a coordinated metal ion has altogether enhanced the broad applicability of carboxamidate ligands in bio-mimetic catalysis. Although the biological precedents with such class of ligands are very less (Nitrile hydratases,...
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#1Wei Li (NKU: Nankai University)H-Index: 27
#2Xian-He Bu (NKU: Nankai University)H-Index: 66
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#1Sana Shaikh (SEU: Southeast University)H-Index: 2
#2Yihan Wang (SEU: Southeast University)
Last. Xuemei Wang (SEU: Southeast University)H-Index: 35
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Abstract Phosphorescent Ir(III) complexes have attracted abundant attention in biomedical research due to their wide ranging properties and organelle specific intracellular imaging. Various types of Ir (III) complexes have been synthesized for visualization and monitoring of subcellular organelles and diagnosis of cancer. The aim of this review is to evaluate the progress of the phosphorescent Ir(III) complexes in bioimaging applications. We intend to highlight the use of Ir(III) complexes for s...
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#1Ana Maria Faísca Phillips (IST: Instituto Superior Técnico)H-Index: 3
#2Hongyi Suo (CAS: Chinese Academy of Sciences)H-Index: 6
Last. Wen-HuaSun (CAS: Chinese Academy of Sciences)H-Index: 53
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Abstract Polyolefins account for two thirds by weight of the global synthetic polymers. There are more than 300 grades of commercial polyolefins, whose properties depend on their microstructures being varied according to the type of catalyst used in the production process and ultimately on the final method of manufacture. Despite having catalytic activities not higher than those of common catalysts, vanadium-based catalysts display several advantages, such as ethylene polymerization for ultra-hi...
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