Ru(ii )-catalyzed C6-selective C–H acylmethylation of pyridones using sulfoxonium ylides as carbene precursors
Abstract
In this study, we describe a method using sulfoxonium ylides as carbene precursors to achieve C6-selective acylmethylation of pyridones catalyzed by a ruthenium(ii) complex. This approach featured mild reaction conditions, moderate to excellent yields, high step economy, and had excellent functional group tolerance with good site selectivity. Besides, gram-scale preparation, synthetic utility, and mechanistic studies were conducted. It offers a...
Paper Details
Title
Ru(ii )-catalyzed C6-selective C–H acylmethylation of pyridones using sulfoxonium ylides as carbene precursors
Published Date
Jan 1, 2020
Journal
Volume
10
Issue
11
Pages
6351 - 6355
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