Coupled reaction mechanism reduction for the hetero-/homogeneous combustion of syngas over platinum

Coupled reduced mechanisms were developed for the hetero-/homogeneous combustion of fuel-lean and fuel-rich H2/CO/O2/N2 mixtures in a Pt-coated planar channel, using a method based on the Directed Relation Graph (DRG) and for a wide range of operating conditions for which detailed measurements are available. It is demonstrated that catalytic and gas-phase reaction mechanisms can be reduced together for all the fuel-lean cases. On the other hand,...