Chain-Breaking Phenolic 2,3-Dihydrobenzo[b ]selenophene Antioxidants: Proximity Effects and Regeneration Studies
Abstract
Phenolic 2,3-dihydrobenzo[b]selenophene antioxidants bearing an OH-group ortho (9), meta (10, 11) and para (8) to the Se were prepared by seleno-Claisen rearrangement/intramolecular hydroselenation. meta-Isomer (11) was studied by X-ray crystallography. The radical-trapping activity and regenerability of compounds 8-11 were evaluated using a two-phase system in which linoleic acid was undergoing peroxidation in the lipid phase while regeneration...
Paper Details
Title
Chain-Breaking Phenolic 2,3-Dihydrobenzo[b ]selenophene Antioxidants: Proximity Effects and Regeneration Studies
Published Date
Oct 9, 2017
Volume
23
Issue
60
Pages
15080 - 15088
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