A Reduced Chemical Kinetic Mechanism for Low Temperature Diesel Combustion and Soot Emissions

A reduced diesel surrogate fuel chemical kinetic mechanism of n-heptane/toluene/1-hexene including poly-aromatic hydrocarbons (PAHs) formation was developed for prediction of the diesel combustion process and soot emissions. The proposed mechanism, which includes 60 species and 123 reactions, agrees well with experimental ignition delays in shock tubes. The proposed mechanism was coupled with the KIVA-3V Release 2 computational fluid dynamics...