New copper(II) 1D polymer containing dimethyl(phenylsulfonyl)amidophosphate: Synthesis, crystal structure and magnetic properties

The reaction of sodium dimethyl(phenylsulfonyl)amidophosphate NaL (HL = C6H5SO2NHP(O)(OCH3)2) with Cu(NO3)2 · 6H2O and o-bpe (1,2-bis(pyridine-2-yl)ethane) in appropriate ratios, afford the formation of 1D coordination polymer [Cu(L)2 · o-bpe]n in good yield. The crystal structures of HL (1) and [Cu(L)2 · o-bpe]n (2) are reported. In the crystal package the molecules of 1 are linked by intermolecular hydrogen bonds formed by the phosphoryl...