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#1İbrahim Kani (Anadolu University)H-Index: 13
#2Hakan Ünver (Anadolu University)H-Index: 4
Abstract In this study, we present the synthesis and full characterization of the dimer Ni(II) complex, [Ni2(dpaa)2(bpy)2(SO4)(H2O)]CH3OH, (dpaa = diphenyl acetic acid, bpy = 2,2’-bipyridine) with an N2O4 donor set and its hydrogenation activity on linear and cyclic alkenes (1-octene, t-2-octene, 1-hexene, cyclohexene, cyclopentene, benzene and styrene) with NaBH4 as a hydrogen source. 1-Octene and 1-hexene were reduced to the corresponding alkanes as the major products (81.3 and 91.2%, respecti...
#1Yu Ge (Soochow University (Suzhou))H-Index: 5
#2Yuan Huang (Soochow University (Suzhou))H-Index: 3
Last. Jinlei Yao (Suzhou University of Science and Technology)H-Index: 1
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Abstract The Schiff base H2bcsdt (H2bcsdt = N1,N3-bis(5-chlorosalicyladehyde) diethylenetriamine) and the β-diketonate Hdbm (Hdbm = dibenzoylmethane) have been employed as a ligand and a pro-ligand to construct a series of Ln(III) complexes. Five mononuclear compounds were synthesized under solvothermal conditions. Single-crystal X-ray diffraction analyses reveal that they are formulated as [Ln(bcsdt)(dbm)(H2O)]·MeCN (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5)). The metal ions in complexes 1–5 ...
#1Marta Karman (University of Gdańsk)
#2Michał Wera (University of Gdańsk)H-Index: 6
Last. Grzegorz Romanowski (University of Gdańsk)H-Index: 13
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Abstract New chiral mononuclear cis-dioxidomolybdenum(VI) complexes, [MoO2(HL1-9)] and [MoO2(HL10)(CH3OH)], have been synthesized by the reaction of MoO2(acac)2 with tetradentate Schiff bases derived from various substituted salicylaldehydes and R(+)-3-amino-1,2-propanediol. All complexes have been characterized by elemental analysis, circular dichroism, electronic, IR and NMR (1H, 13C) spectroscopy. The molecular and crystal structure of [MoO2(HL10)(CH3OH)] elucidated by single-crystal X-ray di...
#1Jamal LasriH-Index: 18
Last. Saied M. SolimanH-Index: 12
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#1Hyungwoo Cho (KNU: Kyungpook National University)H-Index: 6
#2Solhye Choe (KNU: Kyungpook National University)
Last. Saira Nayab (Shaheed Benazir Bhutto University)H-Index: 8
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Abstract A series of Cu(II) complexes, [LnCuCl2] (Ln = LA–LF), supported by N′-aromatic-group-substituted N,N-bis((3,5-dimethyl-1H-pyrazol-1-yl)methylamine ligands have been synthesized. Variations of substituents at the ortho position of the aniline moiety influenced the solid-state structures of these complexes. The X-ray structures of [LnCuCl2] (Ln = LA–LC and LF) revealed that ligands are coordinated in a N,N,N-tridentate fashion to Cu(II) center and adopted a distorted square-pyramidal geom...
#1Ning-Ning JiH-Index: 2
#2Zhi-Qiang ShiH-Index: 2
Last. Gang Li (Zhengzhou University)H-Index: 27
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Abstract The design of new crystalline porous proton-conducing materials becomes an urgent demand because of the increasing demand of energy. Metal–organic frameworks (MOFs), or porous coordination polymers (PCPs), have been proved to be ideal candidates for proton-conducting materials in recent years due to their tailorable structures, good crystallinity, and functionalizable porosity. In order to search for new crystalline porous proton-conducing material with high proton conductivity, a new B...
#1Charanjeet Sen (JU: University of Jammu)
#2Manesh Kumar (JU: University of Jammu)H-Index: 6
Last. Haq Nawaz Sheikh (JU: University of Jammu)H-Index: 9
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Abstract Single crystal diffraction analysis shows the formation of four new coordination polymers (CPs), viz. {[Mn(Pyzdc)(H2O)2]·2H2O}n (1), [Co(Pyzdc)(H2O)2]n (2), [Ni(Pyzdc)(H2O)2]n (3) and [Cd(Pyzdc)]n (4) (where Pyzdc2− stands for the fully-deprotonated pyrazine-2,3-dicarboxylic acid), by the solvothermal self-assembly of the four titled metal(II) nitrates with rigid pyrazine-2,3-dicarboxylic acid. CP 1 crystallizes in the monoclinic P21/c space group, whereas CPs 2, 3 and 4 have orthorhomb...
#1Xiao-Qiang Yao (Ministry of Education)
#2Xiao-Hui Wang (Ministry of Education)
Last. Ming-Dao Zhang (NUIST: Nanjing University of Information Science and Technology)H-Index: 2
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Abstract A trinuclear cobalt-based multifunctional coordination polymer with a dual loop pseudo-rotaxane motif, namely [Co3(DPFE‧H+)2(sdba2−)4(OH−)2](DPFE‧2H+)(CH3CN) (1) , has been synthesized by a mixed ligand strategy under hydrothermal conditions (DPFE = 2,7-di(pyridin-4-yl)-9H-fluorene, H2sdba = 4,4′-sulfonyldibenzoic acid). Compound 1 has 1D + zero-dimensional (0D) → 1D armed pseudo-polyrotaxane character, in which the 1D dual ring chain [Co3(COO−)4(OH−)2(sdba2−)4 is threaded by doubly pro...
#1Tehseen Fatima (QAU: Quaid-i-Azam University)H-Index: 1
#2Imtiaz-ud-Din (QAU: Quaid-i-Azam University)H-Index: 11
Last. Muhammad Ashfaq (UOS: University of Sargodha)H-Index: 1
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Abstract New trinuclear complexes having the general formula [LnCu2(Cl)2(L)2(H2O)2]Cl·H2O, where L (H2L) = Schiff base ligand and Ln = La (1), Nd (2), Sm (3), Gd (4), Tb (5) and Er (6), have been synthesized from the hexadentate ligand (2,2′-{propane-1,3-diylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenol)). The synthesized compounds were characterized by FT-IR and UV–visible spectroscopy, and thermogravimetric analysis. The X-ray structure for 3 completely describes the coordination behavior a...
#1A.K. Patel (MSU: Maharaja Sayajirao University of Baroda)H-Index: 4
#2R.N. Jadeja (MSU: Maharaja Sayajirao University of Baroda)H-Index: 5
Last. Santiago Montero Herrero (Complutense University of Madrid)H-Index: 12
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Abstract New copper(II) hydrazone complexes with (Z)-2-(phenyl(2-(pyridin-2-yl)hydrazono)methyl)pyridine (L) were synthesized and characterized using various physicochemical methods. The geometries of the complexes can be classified as mononuclear and binuclear. The complex 1, [Cu(L)Cl2], is mononuclear whereas the solid-state structure of complex 2 contain a mixture of co-crystals of the mono- and binuclear complexes 2a, [Cu(L)(H2O)(SO4)], and 2b, [(L)Cu-(SO4)2-Cu(L)]. The molecular structure o...
Top fields of study
Crystal structure
Inorganic chemistry