A novel self-assembling of mixed tri- and dibutyltin macrocyclic complex with solvothermal synthesis method

The self-assembled reaction of 2-hydroxynicotinic acid, KOH and tri- n -butyltin chloride in CH 3 OH and H 2 O (V/V = 5:1) under solvothermal condition (150 °C) affords a novel mixed tri- and dibutyltin macrocyclic complex null 1 . Characterization of the complex null 1 null was achieved using elemental analysis, IR, NMR ( 1 H, null 13 C and null 119 Sn) spectroscopy, TGA and X-ray crystallography diffraction analysis. X-ray data revealed that...