Infrared Reflection Absorption Spectroscopy of the Sulfuric Acid Anion on Low and High Index Planes of Palladium
Volume: 106, Issue: 35, Pages: 9107 - 9113
Published: Aug 10, 2002
Abstract
The sulfuric acid anion (HSO4- or SO42-) adsorbed on Pd single-crystal electrodes was studied using infrared reflection absorption spectroscopy (IRAS) in 0.05 M H2SO4 solution. Surfaces examined are flat ones (Pd(111) and Pd(100)) and stepped ones (Pd(110) (= 2(111)−(111)) and Pd(311) (= 2(111)−(100))). All of the surfaces give a single IRAS band around 1200 cm-1 that is assigned to S−O stretching vibration. The integrated band intensity depends...
Paper Details
Title
Infrared Reflection Absorption Spectroscopy of the Sulfuric Acid Anion on Low and High Index Planes of Palladium
Published Date
Aug 10, 2002
Volume
106
Issue
35
Pages
9107 - 9113
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