Emission spectra of polysilanes

Published: Jan 1, 1986
Abstract
We have examined the emission spectra of a variety of polysilanes as thin films and solutions. The solution fluorescence thermochromism provides evidence to support the rotational isomeric state model used to interpret the absorption spectrum. The structured character and low yield of phosphorescence in the alkyl polysilanes suggest that the triplet is the immediate precursor to photochemical scission. The change in character of both...
Paper Details
Title
Emission spectra of polysilanes
Published Date
Jan 1, 1986
Journal
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