A Super-Oxidized Radical Cationic Icosahedral Boron Cluster

Volume: 142, Issue: 30, Pages: 12948 - 12953
Published: Jul 10, 2020
Abstract
While the icosahedral closo-[B12H12]2– cluster does not display reversible electrochemical behavior, perfunctionalization of this species via substitution of all 12 B–H vertices with alkoxy or benzyloxy (OR) substituents engenders reversible redox chemistry, providing access to clusters in the dianionic, monoanionic, and neutral forms. Here, we evaluated the electrochemical behavior of the electron-rich B12(O-3-methylbutyl)12 (1) cluster and...
Paper Details
Title
A Super-Oxidized Radical Cationic Icosahedral Boron Cluster
Published Date
Jul 10, 2020
Volume
142
Issue
30
Pages
12948 - 12953
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