A multifunctional pseudo-polyrotaxane coordination polymer based on the trinuclear cluster [Co3(COO−)4(OH−)2]: Synthesis, structure and properties
Abstract
A trinuclear cobalt-based multifunctional coordination polymer with a dual loop pseudo-rotaxane motif, namely [Co3(DPFE‧H+)2(sdba2−)4(OH−)2](DPFE‧2H+)(CH3CN) (1), has been synthesized by a mixed ligand strategy under hydrothermal conditions (DPFE = 2,7-di(pyridin-4-yl)-9H-fluorene, H2sdba = 4,4′-sulfonyldibenzoic acid). Compound 1 has 1D + zero-dimensional (0D) → 1D armed pseudo-polyrotaxane character, in which the 1D dual ring chain...
Paper Details
Title
A multifunctional pseudo-polyrotaxane coordination polymer based on the trinuclear cluster [Co3(COO−)4(OH−)2]: Synthesis, structure and properties
Published Date
Aug 1, 2020
Journal
Volume
186
Pages
114611 - 114611
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