Thermodynamic properties, crystal structure and phase relations of pushcharovskite [Cu(AsO<sub>3</sub>OH)(H<sub>2</sub>O) ⋅ 0.5H<sub>2</sub>O], geminite [Cu(AsO<sub>3</sub>OH)(H<sub>2</sub>O)] and liroconite [Cu<sub>2</sub>Al(AsO<sub>4</sub>)(OH)<sub>4</sub> ⋅ 4H<sub&…
Abstract
. The phases pushcharovskite, geminite and liroconite were synthesized or acquired and characterized by powder X-ray diffraction, infrared spectroscopy, electron microprobe analysis, thermogravimetric analysis and optical emission spectrometry, as needed. Their thermodynamic properties were determined by a combination of acid-solution calorimetry and relaxation calorimetry, resulting in Gibbs free energies of formation (ΔfGo, all values in...
Paper Details
Title
Thermodynamic properties, crystal structure and phase relations of pushcharovskite [Cu(AsO<sub>3</sub>OH)(H<sub>2</sub>O) ⋅ 0.5H<sub>2</sub>O], geminite [Cu(AsO<sub>3</sub>OH)(H<sub>2</sub>O)] and liroconite [Cu<sub>2</sub>Al(AsO<sub>4</sub>)(OH)<sub>4</sub> ⋅ 4H<sub&…
Published Date
May 11, 2020
Volume
32
Issue
3
Pages
285 - 304
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