Chirality and Magnetic Properties of One-dimensional Ln (Ln = Gd, Dy) Polymers

The usage of the achiral ligand, in lanthanide chemistry, successfully obtained two series of chiral lanthanide complexes, formulated d ‐ and l ‐{Gd[IN][HIN][CH 2 OCH 2 O]} n (abbreviated as Gd ) and d ‐ and l ‐{Dy[IN][HIN][CH 2 OCH 2 O]} n (abbreviated as Dy , HIN = isonicotinic acid). Crystallographic researches determined that four compounds are all one‐dimensional (1D) chain structures and crystallized in a chiral space group. In addition,...