A Reduced‐Symmetry Heterobimetallic [PdPtL4]4+ Cage: Assembly, Guest Binding, and Stimulus‐Induced Switching
Volume: 59, Issue: 27, Pages: 11101 - 11107
Published: Apr 30, 2020
Abstract
A strategy is presented that enables the quantitative assembly of a heterobimetallic [PdPtL 4 ] 4+ cage. The presence of two different metal ions (Pd II and Pt II ) with differing labilities enables the cage to be opened and closed selectively at one end upon treatment with suitable stimuli. Combining an inert Pt II tetrapyridylaldehyde complex with a suitably substituted pyridylamine and Pd II ions led to the assembly of the cage. 1 H and DOSY...
Paper Details
Title
A Reduced‐Symmetry Heterobimetallic [PdPtL4]4+ Cage: Assembly, Guest Binding, and Stimulus‐Induced Switching
Published Date
Apr 30, 2020
Volume
59
Issue
27
Pages
11101 - 11107
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