Diversity Oriented Preparation of Pillar[5]arene‐Containing [2]Rotaxanes by a Stopper Exchange Strategy
Abstract
Rotaxane building blocks bearing 3,5‐bis(trifluoromethyl) benzenesulfonate (BTBS) stoppers have been efficiently prepared from a pillar[5]arene derivative, 3,5‐bis(trifluoromethyl) benzenesulfonyl chloride (BTBSCl) and different diols, namely 1,10‐decanediol and 1,12‐dodecanediol. The BTBS moieties of these compounds are good leaving groups and stopper exchange reactions could be achieved by treatment with different nucleophiles thus affording...
Paper Details
Title
Diversity Oriented Preparation of Pillar[5]arene‐Containing [2]Rotaxanes by a Stopper Exchange Strategy
Published Date
Mar 10, 2020
Journal
Volume
9
Issue
4
Pages
393 - 400
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