Zinc-rich and copper-bearing amphiboles from sulfide-free ore occurrences of the Pelagonian Massif, Republic of North Macedonia

This paper describes specific features of isomorphism of unusual amphiboles containing up to 23 wt% ZnO and up to 1.3 wt% CuO from sulfide-free metasomatic rocks of the “Mixed Series” metamorphic complex, Pelagonian Massif, Republic of North Macedonia, in which chalcophile elements (Pb, Cu, Zn, Sb, As) occur in high concentrations in the form of oxides and oxysalts. The studied amphiboles belong to six mineral species: magnesio-riebeckite,...