Study of ozone sensitized diethyl carbonate oxidation at low and intermediate temperatures

The oxidation of diethyl carbonate (DEC) with O3 additions was studied in an atmospheric jet stirred reactor (JSR) at 400-850K in this work. It was seen that DEC had no low temperature reactivity without O3 addition in experiment, while the oxidation began from 450K with O3 additions. A DEC/O3 model was developed in this work and pathway analysis showed that the O3 assisted low temperature oxidation of DEC came from the reaction of DEC+O instead...