Preparation of Micro and Nanorod Metal Organic Framework Through Coordination Modulation Method as Precursor for Micro and Nanorod NiO

In the present work, micro and nanorods of a three dimensional metal organic framework, [Ni2(BDC)2(DABCO)]·DMF4·H2O4(1), DABCO (DABCO = 1,4-diazabicyclo[2.2.2] octane), and BDC (BDC = 1,4-benzenedicarboxylic acid), were synthesized through coordination modulation method in the presence of various amounts of acetic acid. Then the effect of acetic acid amount on the size of the synthesized materials was investigated. The prepared micro and...