Highly selective and efficient oxidation of benzylic alcohols with sulfate radical over metal-organic frameworks

Volume: 903, Pages: 120995 - 120995
Published: Dec 1, 2019
Abstract
phosphonate-based metal-organic frameworks known as STA-12(M) (M = Mn, Fe, Co, Ni), show excellent catalytic activity towards oxidation of aromatic alcohols to aldehydes with Na2S2O4/TBHP (tert-Butyl hydroperoxide) mixture. The STA-12(Fe) exhibited higher oxidation activity than other MOFs used in this work. Aldehydes were produced selectively in high yields under mild conditions at desired times. Recyclability for fourteen runs, without any...
Paper Details
Title
Highly selective and efficient oxidation of benzylic alcohols with sulfate radical over metal-organic frameworks
Published Date
Dec 1, 2019
Volume
903
Pages
120995 - 120995
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