Chemometric Evaluation of Repeatability Using the Autocorrelation Method in High-Performance Liquid Chromatography with Ultraviolet Detection

The mixed random processes of the first order autoregressive process (AR(1)) and white noise have been proved to provide a good approximation of baseline noise in a variety of analytical instruments, and may therefore be useful for estimating precision profiles. This study aims to examine a recently proposed autocorrelation method for estimating three noise parameters involved in the mixed processes (two for AR(1) and one for white noise) of...