Bis‐aroylhydrazone based on 2,2′‐bis substituted diphenylamine for synthesis of new binuclear organotin (IV) complexes: Spectroscopic characterization, crystal structures, in vitro DNA‐binding, plasmid DNA cleavage, PCR and cytotoxicity against MCF7 cell line

Volume: 33, Issue: 11
Published: Aug 27, 2019
Abstract
New dinuclear organotin (IV) complexes, Me4Sn2L, Ph4Sn2L and Bu4Sn2L, have been synthesized from reaction of R2SnCl2 (R = Me, Ph and Bu) with a 2,2′-bis-substituted diphenylamine arοylidene hydrazone, H4L. The synthesized compounds were investigated by elemental analysis and infrared, 1H-NMR and 119Sn-NMR spectroscopy. The structures of H4L, Me4Sn2L and Bu4Sn2L were also confirmed by X-ray crystallography. H4L molecules adopt (E)-configuration...
Paper Details
Title
Bis‐aroylhydrazone based on 2,2′‐bis substituted diphenylamine for synthesis of new binuclear organotin (IV) complexes: Spectroscopic characterization, crystal structures, in vitro DNA‐binding, plasmid DNA cleavage, PCR and cytotoxicity against MCF7 cell line
Published Date
Aug 27, 2019
Volume
33
Issue
11
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