Bis‐aroylhydrazone based on 2,2′‐bis substituted diphenylamine for synthesis of new binuclear organotin (IV) complexes: Spectroscopic characterization, crystal structures, in vitro DNA‐binding, plasmid DNA cleavage, PCR and cytotoxicity against MCF7 cell line
Abstract
New dinuclear organotin (IV) complexes, Me4Sn2L, Ph4Sn2L and Bu4Sn2L, have been synthesized from reaction of R2SnCl2 (R = Me, Ph and Bu) with a 2,2′-bis-substituted diphenylamine arοylidene hydrazone, H4L. The synthesized compounds were investigated by elemental analysis and infrared, 1H-NMR and 119Sn-NMR spectroscopy. The structures of H4L, Me4Sn2L and Bu4Sn2L were also confirmed by X-ray crystallography. H4L molecules adopt (E)-configuration...
Paper Details
Title
Bis‐aroylhydrazone based on 2,2′‐bis substituted diphenylamine for synthesis of new binuclear organotin (IV) complexes: Spectroscopic characterization, crystal structures, in vitro DNA‐binding, plasmid DNA cleavage, PCR and cytotoxicity against MCF7 cell line
Published Date
Aug 27, 2019
Volume
33
Issue
11
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