Three-Dimensional Co(II)-Metal–Organic Frameworks with Varying Porosities and Open Metal Sites toward Multipurpose Heterogeneous Catalysis under Mild Conditions
Abstract
In recent years, heterogeneous catalysis has become one of the most active domains in the research of metal–organic frameworks (MOFs). Here, two three-dimensional (3D) Co(II)-MOFs with open metal sites and exposed azo functionality on the MOF backbone have been constructed via mixed ligand assembly. Both the MOFs, 1 {[Co2(1,4-NDC)2(L)(H2O)2(μ2-H2O)]·(DMF)2(H2O)}n and 2 {[Co(fma)(L)(H2O)2]·S}n [1,4-NDC = 1,4-naphthalene dicarboxylic acid, fma =...
Paper Details
Title
Three-Dimensional Co(II)-Metal–Organic Frameworks with Varying Porosities and Open Metal Sites toward Multipurpose Heterogeneous Catalysis under Mild Conditions
Published Date
Aug 15, 2019
Journal
Volume
19
Issue
9
Pages
5343 - 5353
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