Metal and Oxidant-Free Brønsted Acid-Mediated Cascade Reaction to Substituted Benzofurans

Substituted hydroxy-benzofurans are easily accessible by treatment of resorcinols and 1,2-diaza-1,3-dienes (DDs) under acidic conditions. The reaction happens through an uncommon Michael reaction between aromatic derivatives as aromatic C(sp2)–H nucleophiles and DDs as acceptors. Also, the behavior of different phenols and 2-naphthol was...