Higher Order Vibronic Sidebands of Chlorophyll a and Bacteriochlorophyll a for Enhanced Excitation Energy Transfer and Light Harvesting

Optical absorption and fluorescence spectra of molecules in condensed phases often show extensive sidebands. Originating from electron–vibrational and electron–phonon couplings, these spectral tails bear important information on the dynamics of electronic states and processes the molecules are involved in. The vibronic sidebands observed in conjugate Qy absorption and fluorescence spectra of chlorophyll a and bacteriochlorophyll a are relatively...