Bulk Acyclic Diene Metathesis Polycondensation

Volume: 220, Issue: 15
Published: Jul 9, 2019
Abstract
Bulk acyclic diene metathesis (ADMET) polymerization performed in the melt at temperatures up to 175 °C is completed using a cyclic (alkyl)(amino) carbene (CAAC) ruthenium‐based Grubbs catalyst. High temperature stability is investigated at temperatures well above conventional ADMET chemistry, leading to the highest weight‐average molecular weights ever achieved for any ADMET polymer. A study of isomerization tendency (double bond migration) is...
Paper Details
Title
Bulk Acyclic Diene Metathesis Polycondensation
Published Date
Jul 9, 2019
Volume
220
Issue
15
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