Copper(II)/Tin(II) Reagent for Allylation, Propargylation, Alkylation, and Benzylation of Disulfides and Elemental Sulfur: New Insight into the “Copper Effect”†
Abstract
Organic bromides and iodides react with diorganodisulfides in the presence of stannous chloride and catalytic cupric halide, giving rise to corresponding unsymmetrical sulfides. Similar reactions but with elemental sulfur provide trisulfides and tetrasulfides. The reactions proceed by copper thiolate as principal reactive...
Paper Details
Title
Copper(II)/Tin(II) Reagent for Allylation, Propargylation, Alkylation, and Benzylation of Disulfides and Elemental Sulfur: New Insight into the “Copper Effect”†
Published Date
Jan 1, 2001
Journal
Volume
20
Issue
1
Pages
157 - 162
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