Hydrothermal synthesis, characterization and properties of a d¹⁰ metal coordination polymer with a layered structure based on carboxyphosphinate ligand, 4,4^′-bipyridine and four-coordinated zinc ion

Hydrothermal reaction of Zn(NO3)2 · 6 H2O with 2-carboxyethyl(phenyl)phosphinate (H2L) and 4,4'-bipyridine (4,4′-bipy) led to a novel zinc(II) carboxyphosphinate [ZnL(4,4′-bipy)0.5]n (1). The zinc ion is tetrahedrally coordinated by two phosphinate oxygen atoms, one carboxylate oxygen atom, and one nitrogen atom of 4,4′-bipy ligand. The L2- ligand and zinc ion can be seen as three- and four-connected nodes, respectively. Compound 1 shows a...