Dinuclear and Mononuclear Rhenium Coordination Compounds upon Employment of a Schiff-Base Triol Ligand: Structural, Magnetic, and Computational Studies

Volume: 58, Issue: 13, Pages: 8596 - 8606
Published: Jun 10, 2019
Abstract
The 1:1 reaction of trans-[ReIIICl3(PPh3)2(MeCN)] with 2-(β-naphthalideneamino)-2-hydroxymethyl-1-propanol, H3L, in toluene gave the dinuclear complex [ReIII2Cl4(HL)(PPh3)]·2C7H8 (1·2C7H8), while the 1:2 reaction led to the formation of complex [ReIVCl2(HL)(PPh3)] (2). In both species, the Schiff-base ligand exists in its doubly deprotonated form, HL2–, forming chelate rings around the metallic centers. In addition, 1·2C7H8 displays a unique...
Paper Details
Title
Dinuclear and Mononuclear Rhenium Coordination Compounds upon Employment of a Schiff-Base Triol Ligand: Structural, Magnetic, and Computational Studies
Published Date
Jun 10, 2019
Volume
58
Issue
13
Pages
8596 - 8606
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