Synthesis of enantiopure furo[2,3-b]pyrroles
Abstract
A simple method for the preparation of enantiopure furo[2,3-b]pyrroles, a rare class of concave bicyclic nitrogen and oxygen heterocycle, in promising yield has been developed. The 3-substituted pyrrolidinediones prepared from (2S,3S)-tetrahydro-3-hydroxy-5-oxo-2,3-furandicarboxylic acid (Garcinia acid) have been cyclized diastereo as well as enantioselectively to furo[2,3-b]pyrroles. The cyclization follows Baldwin’s...
Paper Details
Title
Synthesis of enantiopure furo[2,3-b]pyrroles
Published Date
Oct 1, 2014
Journal
Volume
55
Issue
42
Pages
5822 - 5824
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