Heteroaromatic Aldehydes with Unprecedented Catalytic Performance in Selective Radical Reactions: Synthesis of α‐Aminophosphonate Scaffolds

Heterocyclic compounds have gained immense importance because of their low resonance energy and strong hydrogen‐bonding abilities, which provide good catalytic potential in a variety of organic transformations. Herein an unexpected metal‐free catalytic performance of heteroaromatic aldehydes has been reported. Accordingly, a unique method for the synthesis of new scaffolds of peptidomimetic compounds, α‐aminophosphonates has been developed,...