Stepwise oxidations of a nickel(ii )–iron(iii ) heterobimetallic porphyrin dimer: structure, spectroscopic and theoretical investigation
Abstract
A novel nickel(ii )–iron(iii ) heterobimetallic ethene-bridged porphyrin dimer has been synthesized which upon two-electron oxidation produces a nickel(ii )–iron(iii ) dication diradical complex where radicals undergo extensive conjugation through the bridge for all possible...
Paper Details
Title
Stepwise oxidations of a nickel(ii )–iron(iii ) heterobimetallic porphyrin dimer: structure, spectroscopic and theoretical investigation
Published Date
Jan 1, 2019
Journal
Volume
48
Issue
27
Pages
10089 - 10103
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Notes
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