Through‐Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: AgII⋅⋅⋅AgII, AgII⋅⋅⋅AgIII, and AgIII⋅⋅⋅AgIIIMetallophilic Interactions

Volume: 25, Issue: 43, Pages: 10098 - 10110
Published: Jul 18, 2019
Abstract
Metallophilic interactions between closed-shell metal ions are becoming a popular tool for a variety of applications related to high-end materials. Heavier d8 transition-metal ions are also considered to have a closed shell and can be involved in such interactions. There is no systematic investigation so far to estimate the structure and energy characteristics of metallophilic interactions in AgII /AgII (d9 /d9 ), AgIII /AgIII (d8 /d8 ), and...
Paper Details
Title
Through‐Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: AgII⋅⋅⋅AgII, AgII⋅⋅⋅AgIII, and AgIII⋅⋅⋅AgIIIMetallophilic Interactions
Published Date
Jul 18, 2019
Volume
25
Issue
43
Pages
10098 - 10110
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