Original paper
Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii ) porphyrin dimer
Abstract
A complete reversal of the spin state of iron(iii) is observed upon a small change to the diporphyrin bridge from ethane to ethene by keeping all other factors intact. Combined analysis using single crystal X-ray structure determination, Mössbauer, variable-temperature magnetic, 1H NMR and EPR studies has confirmed the spin states of iron(iii) complexes both in solid and solution...
Paper Details
Title
Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii ) porphyrin dimer
Published Date
Jan 1, 2019
Journal
Volume
48
Issue
19
Pages
6353 - 6357
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Notes
History