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Development of sustainable acid blue 113 dye adsorption system using nutraceutical industrial Tribulus terrestris spent

Published on Apr 1, 2019
· DOI :10.1007/s42452-018-0125-5
Mohammed A. H. Dhaif Allah (University of Mysore), Syed Noeman Taqui2
Estimated H-index: 2
(UM: University of Malaya)
+ 1 AuthorsAkheel Ahmed Syed13
Estimated H-index: 13
(University of Mysore)
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Abstract
First-ever study was done using a low-cost Tribulus terrestris spent, a by-product of a nutraceutical industry as an effective biosorbent for removing acid blue 113 (AB113) from aqueous media. The effect of various factors such as pH, dye concentration, amount of adsorbent, particle size of adsorbent, contact time as also temperature on adsorption have been studied. Analysis of equilibrium data was done by using two number of two-parameter and six number of three-parameter isotherm models. Kinetic studies on adsorption were done using models like pseudo-first order and pseudo-second order. Webber–Morris and Dumwald–Wagner diffusion models helped to study diffusion. Determination and evaluation were also done for change in enthalpy (ΔH°), entropy (ΔS°), and Gibbs free energy (ΔG°) of adsorption system. Scanning electron microscopy, Fourier transform infrared spectroscopy and determination of point of zero-charge were carried out for surface characterization of the adsorbent. We have used a two-level fractional factorial experimental design approach and subsequently analysis of variance to define a statistically developed model from which we obtained values of above parameters which yielded maximum possible adsorption as 93.00 mg/g. The investigations proved that nutraceutical industrial T. terrestris spent is both cost-effective and an efficient biosorbent for the remediation of AB113 dye from aqueous system and textile industrial effluent.
  • References (65)
  • Citations (1)
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References65
Newest
Published on Sep 19, 2018in International Journal of Phytoremediation 2.24
Razia Sulthana1
Estimated H-index: 1
(University of Mysore),
Syed Noeman Taqui2
Estimated H-index: 2
(UM: University of Malaya)
+ 2 AuthorsAkheel Ahmed Syed13
Estimated H-index: 13
(University of Mysore)
ABSTRACTDye pollutants from research laboratories are one of the major sources for environmental contamination. In the present study, a nutraceutical industrial fennel seed spent (NIFSS) was explored as potential adsorbent for removal of ethidium bromide (EtBr) from aqueous solution. The adsorbent was characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Through batch experiments, the operating variables like initial dye concentration, adsorbent ...
Published on Jul 3, 2017in International Journal of Phytoremediation 2.24
Syed Noeman Taqui2
Estimated H-index: 2
(UM: University of Malaya),
Rosiyah Yahya20
Estimated H-index: 20
(UM: University of Malaya)
+ 2 AuthorsAkheel Ahmed Syed13
Estimated H-index: 13
(University of Mysore)
ABSTRACTFennel seed spent (FSS)—an inexpensive nutraceutical industrial spent has been used as an efficient biosorbent for the removal of Congo red (CR) from aqueous media. Results show that the conditions for maximum adsorption would be pH 2-4 and 30°C were ideal for maximum adsorption. Based on regression fitting of the data, it was determined that the Sips isotherm (R2 = 0.994, χ2 = 0.5) adequately described the mechanism of adsorption, suggesting that the adsorption occurs homogeneously with...
Published on Mar 1, 2017in International Journal of Environmental Research 1.49
Pradeep Kumar Papegowda1
Estimated H-index: 1
(University of Mysore),
Akheel Ahmed Syed1
Estimated H-index: 1
(UM: University of Malaya)
In the present research work Saw palmetto spent (SPS) was used to remove Methylene blue (MB) from aqueous solution economically. SEM and FTIR Studies were made to understand the Morphological properties of the adsorbent. Various parameters of adsorption such as, initial dye concentration, contact time, pH and temperature were studied. Langmuir, Freundlich and Temkin isotherm models were used to explain the adsorption behaviour. Pseudo-first order, pseudo-second order kinetic models and Intra-par...
Published on Dec 25, 2016in Desalination and Water Treatment 1.23
Hung-Yee Shu4
Estimated H-index: 4
(HK: Hungkuang University),
Shi-Wei Huang3
Estimated H-index: 3
(HK: Hungkuang University),
Meng-Ke Tsai1
Estimated H-index: 1
(HK: Hungkuang University)
AbstractSulfate radical-based advanced oxidation processes (SR-AOPs) are powerful technologies to treat various pollutants. Among these SR-AOPs, UV/persulfate (UV/PS) and UV/Oxone were chosen to degrade and mineralize Acid Blue 113 (AB113) wastewater for their strong reactivity. The experimental setup was designed identical to compare two processes. Operating parameters such as oxidant dosage, UV intensity, initial dye concentration, and pH were studied to evaluate their effects on degradation a...
Published on Oct 1, 2016in International Journal of Nanoscience
Thurlapathi Vl Thejaswini1
Estimated H-index: 1
,
D. Prabhakaran4
Estimated H-index: 4
The present work deals with the synthesis of bi-continuous macro and mesoporous crack-free titania–silica monoliths, with well-defined structural dimensions and high surface area. The work also highlights their potential photocatalytic environmental applications. The highly ordered titania–silica monoliths are synthesized through direct surface template method using organic precursors of silica and titania in the presence of surface directing agents such as pluronic P123 and PEG, under acetic ac...
Published on Sep 1, 2016in Journal of Thermoplastic Composite Materials 1.34
Murtuza Ali Syed4
Estimated H-index: 4
(University of Mysore),
Akheel Ahmed Syed13
Estimated H-index: 13
(University of Mysore)
To enhance biodegradability of plastics and to utilize Centella spent (CTS) gainfully, green composites were prepared using high-density polyethylene (HDPE) and CTS. The green composites were fabricated by extrusion, followed by injection molding. HDPE/CTS composites were fabricated with 10, 20, and 30 wt% of CTS using maleic anhydride-grafted-polyethylene (MA-g-PE) as compatibilizer. The fabricated composites were tested for physicomechanical and tribological properties, which included water ab...
Published on Aug 1, 2016in Polymer Composites 2.27
Murtuza Ali Syed4
Estimated H-index: 4
(University of Mysore),
Akheel Ahmed Syed13
Estimated H-index: 13
(University of Mysore)
This study was aimed at fabrication of green composites of polypropylene (PP) matrix 5, 10, 15, and 20 wt% of saw palmetto spent (SPS) (a spent of nutraceuticals) as filler material. Two wt% organically modified montmorillonite clay (MMT) was used as a co-filler in all formulations and composites were fabricated by melt blending. The fabricated PP/SPS/MMT composites were characterized for physicomechanical and tribological properties. Improvement in tensile modulus of the composites was noticed ...
Published on Apr 8, 2016in Desalination and Water Treatment 1.23
Hung-Yee Shu4
Estimated H-index: 4
(HK: Hungkuang University),
Ming-Chin Chang4
Estimated H-index: 4
(HK: Hungkuang University),
Shi-Wei Huang3
Estimated H-index: 3
AbstractA UV/Oxone advanced oxidation process was proposed to degrade and mineralize a synthesized Acid Blue 113 (AB113) dyeing wastewater. Various operating parameters which affected the removal efficiencies of AB113 and total organic carbon (TOC) such as reaction time, Oxone dosage, initial AB113 concentration, initial pH, and UV intensity were studied. Results presented effective removal of AB113 azo dye by UV/Oxone process based on both AB113 and TOC indicators. The reaction kinetics was sho...
Published on Apr 8, 2016in Desalination and Water Treatment 1.23
Hung-Yee Shu4
Estimated H-index: 4
(HK: Hungkuang University),
Ming-Chin Chang4
Estimated H-index: 4
(HK: Hungkuang University),
Jian-Jun Liu2
Estimated H-index: 2
(HK: Hungkuang University)
AbstractIn this study, effectively reductive decolorization of wastewater with synthesized C.I. Acid Blue 113 (AB113) was obtained by nanoscale particles of zero-valent iron (NZVI), bimetallic iron/nickel (nFe/Ni) and iron/zinc (nFe/Zn) which were prepared in the laboratory with large surface area and reductive potential. The particle size was identified less than 100 nm by field emission scanning electron microscope (FESEM) that nickel was homogeneously distributed with iron element by FESEM ma...
Cited By1
Newest
Published on May 28, 2019in International Journal of Environmental Research 1.49
Syed Noeman Taqui2
Estimated H-index: 2
(UM: University of Malaya),
Rosiyah Yahya20
Estimated H-index: 20
(UM: University of Malaya)
+ 2 AuthorsAkheel Ahmed Syed13
Estimated H-index: 13
(University of Mysore)
The potential usage of coriander seed spent which is a nutraceutical industrial by-product in the removal of Acid Black 52 (AB52) dye from aqueous solutions was evaluated with respect to various experimental parameters including pH, initial dye concentration, adsorbent dosage, adsorbent particle size, duration of contact time and temperature. The optimal qe value at pH 2, pH 7 and pH 12 was 432 mg g−1, 164 mg g−1 and 220 mg g−1, respectively. Two-level fractional factorial experimental design mo...