Synthesis, Characterization and Catalytic Properties of Benzylphosphonate-aminethylphosphine-Pd(II), Cu(II), Ru(II) and V(IV) Complexes

The novel 4-(bis((diphenylphosphino)methyl)amino)diethyl-benzylphosphonate (L, ligand) and its Pd(II), Cu(II), Ru(II) and oxo-V(IV) complexes were synthesized under nitrogen atmosphere using Schlenk technique. The ligand and the complexes were characterized with (1H)-31P-NMR, FT-IR, TG/DTA, elemental analysis (C, H, N %), ICP-OES (Metal %), cyclic voltammetry (CV) and photoluminescence techniques. Whereas proton decoupled 31P resonance peak of...