Dynamic Kinetic Resolution of Aldehydes by Hydroacylation
Abstract
We report a dynamic kinetic resolution (DKR) of chiral 4-pentenals by olefin hydroacylation. A primary amine racemizes the aldehyde substrate via enamine formation and hydrolysis. Then, a cationic rhodium catalyst promotes hydroacylation to generate α,γ-disubstituted cyclopentanones with high enantio- and...
Paper Details
Title
Dynamic Kinetic Resolution of Aldehydes by Hydroacylation
Published Date
Feb 27, 2019
Journal
Volume
58
Issue
14
Pages
4705 - 4709
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