Multifrequency EPR, SQUID, and DFT Study of Cupric Ions and Their Magnetic Coupling in the Metal–Organic Framework Compound ∞3[Cu(prz–trz–ia)]
Volume: 122, Issue: 46, Pages: 26642 - 26651
Published: Nov 8, 2018
Abstract
Multifrequency electron paramagnetic resonance (EPR) spectroscopy, magnetic susceptibility measurements, and density functional theory (DFT) have been employed to characterize the magnetic properties of Cu2+ ions and their magnetic interactions in the porous metal–organic framework compound ∞3[Cu(prz–trz–ia)]. Two distinct cupric ion species were found to contribute to the overall magnetic susceptibility of the polycrystalline material. The...
Paper Details
Title
Multifrequency EPR, SQUID, and DFT Study of Cupric Ions and Their Magnetic Coupling in the Metal–Organic Framework Compound ∞3[Cu(prz–trz–ia)]
Published Date
Nov 8, 2018
Volume
122
Issue
46
Pages
26642 - 26651
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