Thermokinetic Studies in the Polycarbosilane–Oligosilazane–Rolivsan System

Volume: 91, Issue: 6, Pages: 1035 - 1043
Published: Jun 1, 2018
Abstract
Curing and pyrolysis of ceramic-forming systems based on polycarbosilane, oligovinylsilazane, and Rolivsan® were studied by differential scanning calorimetry, thermal gravimetric analysis, and IR spectroscopy. Mechanisms of three-step curing were suggested. The kinetics of curing, occurring without weight changes, was described assuming that the conversion rate is proportional to the thermal flux. In the case of pyrolysis accompanied by the...
Paper Details
Title
Thermokinetic Studies in the Polycarbosilane–Oligosilazane–Rolivsan System
Published Date
Jun 1, 2018
Volume
91
Issue
6
Pages
1035 - 1043
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