Salt Partitioning in Complex Coacervation of Symmetric Polyelectrolytes
Abstract
We perform a general thermodynamic analysis for the
salt partitioning behavior in the coexisting phases for symmetric
mixtures of polycation and polyanion solutions. We find that salt
partitioning is determined by the competition between two factors
involving the ratio of the polyelectrolyte concentration in the coacervate phase to that in the supernatant phase and the difference in the exchange excess chemical potential Δμ_(ex) -- the...
Paper Details
Title
Salt Partitioning in Complex Coacervation of Symmetric Polyelectrolytes
Published Date
Jul 18, 2018
Journal
Volume
51
Issue
15
Pages
5586 - 5593
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