A Unique LnIII{[3.3.1]GaIII Metallacryptate} Series That Possesses Properties of Slow Magnetic Relaxation and Visible/Near‐Infrared Luminescence
Volume: 24, Issue: 42, Pages: 10773 - 10783
Published: Jun 27, 2018
Abstract
A new family of [3.3.1] metallacryptates with the general composition [LnGa 6 (H 2 shi)(Hshi)(shi) 7 (C 5 H 5 N)] ( Ln‐1 ; shi 3− =salicylhydroximate; Ln = Pr, Nd, Sm–Yb) has been synthesized and characterized. Ln‐1 display both interesting magnetic and luminescent properties. Sm‐1 has sharp emission bands in the visible and the near‐infrared (NIR) regions with quantum yield values ( ) of 1.64(9) and 5.5(2) . 10 −2 %, respectively. Tb‐1 exhibits...
Paper Details
Title
A Unique LnIII{[3.3.1]GaIII Metallacryptate} Series That Possesses Properties of Slow Magnetic Relaxation and Visible/Near‐Infrared Luminescence
Published Date
Jun 27, 2018
Volume
24
Issue
42
Pages
10773 - 10783
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