Argentophilic Interactions in Solution: An EXAFS Study of Silver(I) Nitrene Transfer Catalysts
Abstract
Silver(I) catalysts have been developed for nitrene transfer reactions such as aziridination and C–H insertion. For some catalysts, structures determined by X-ray crystallography reveal dimers with silver–silver interactions, leading to mechanistic speculation about the potential role of dinuclear silver complexes in catalysis. However, it is often unclear if the silver–silver interactions persist in solution. Here we use EXAFS to directly...
Paper Details
Title
Argentophilic Interactions in Solution: An EXAFS Study of Silver(I) Nitrene Transfer Catalysts
Published Date
May 10, 2018
Journal
Volume
57
Issue
10
Pages
5720 - 5722
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