3-Methyl-1-{(E)-[1-(4-methylpyridin-2-yl)ethylidene]amino}thiourea: crystal structure and Hirshfeld surface analysis

The title disubstituted thiourea derivative, C 10 H 14 N 4 S, features an almost planar imine ( E configuration, C 3 N) core flanked by thiourea (CN 2 S) and methylpyridyl (C 5 N) residues (each plane has a r.m.s. deviation of the respective fitted atoms of 0.0066 Å). The dihedral angles between the core and the thiourea and pyridyl residues are 20.25 (8) and 7.60 (9)°, respectively, indicating twists in the molecule; the dihedral angle between...