Accurate Frequency Determination of Vibration–Rotation and Rotational Transitions of SiH⁺

The fundamental 28SiH+ ion has been characterized in a collaborative work, utilizing a hollow-cathode-discharge laser-spectrometer and a cryogenic ion trap spectrometer. Twenty-three vibration-rotation transitions around 4.75 μm have been detected with high accuracy. This has facilitated the first direct measurement of the pure rotational transition J = 1 ← 0 at 453056.3632(4) MHz in the trap spectrometer. The measured and accurately predicted...