Efficient Heterogeneous CO₂ to CO Conversion with a Phosphonic Acid Fabricated Cofacial Iron Porphyrin Dimer

For developing renewable fuels and controlling global warming, catalyst promoted conversion of CO2 to CO is essential. Numerous CO2 to CO conversion molecular catalysts have shown very high activity and stability. For large-scale conversion, immobilization of the molecular catalysts to conducting electrodes is essential. Several efficient molecular catalysts have been immobilized to conducting electrodes via physical bonds. We found that...