Intermacrocyclic Interaction Triggers Facile One‐Pot Synthesis of a Chlorin–Porphyrin Heterodimer
Volume: 23, Issue: 54, Pages: 13415 - 13422
Published: Aug 23, 2017
Abstract
This work reports a highly facile one-pot synthesis of a new series of fully π-conjugated unsymmetric chlorin-porphyrin heterodimers with quantitative yields by utilizing intermacrocyclic interactions. One-electron oxidations of dicopper(II) and dipalladium(II) porphyrin dimers using mild oxidants such as iodine at room temperature resulted in the formation of a strongly interacting cofacial mixed-valent π-cation radical dimers. The radical,...
Paper Details
Title
Intermacrocyclic Interaction Triggers Facile One‐Pot Synthesis of a Chlorin–Porphyrin Heterodimer
Published Date
Aug 23, 2017
Volume
23
Issue
54
Pages
13415 - 13422
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