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doi.org/10.1021/acs.inorgchem.6b01832

The Nature of the Bridging Anion Controls the Single-Molecule Magnetic Properties of DyX4M 12-Metallacrown-4 Complexes

..., Vincent L. Pecoraro
76
Inorganic Chemistry4.60
Volume: 55, Issue: 20, Pages: 10597 - 10607
Published: Oct 5, 2016
Abstract
A family of DyX4M(12-MCMnIII(N)shi-4) compounds were synthesized and magnetically characterized (X = salicylate, acetate, benzoate, trimethylacetate, M = NaI or KI). The bridging ligands were systematically varied while keeping the remainder of the MC-geometry constant. The type of monovalent cation, necessary for charge balance, was also altered. The dc magnetization and susceptibility of all compounds were similar across the series. Regardless...
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Paper Details
Title
The Nature of the Bridging Anion Controls the Single-Molecule Magnetic Properties of DyX4M 12-Metallacrown-4 Complexes
DOI
doi.org/10.1021/acs.inorgchem.6b01832
Published Date
Oct 5, 2016
Journal
Inorganic Chemistry
Volume
55
Issue
20
Pages
10597 - 10607
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