Spin Modulation in Highly Distorted Fe III Porphyrinates by Using Axial Coordination and Their π‐Cation Radicals

Volume: 2016, Issue: 21, Pages: 3441 - 3453
Published: Jun 15, 2016
Abstract
A series of five-coordinate FeIII octaaryltetraphenylporphyrins [FeIII(por)(X)] (X = Cl, I, I3, ClO4, or SO3CF3) and their 1 e–-oxidized complexes [FeIII(por·)(X)(Y)] (X = Cl, I, ClO4, or SO3CF3; Y = SbCl6, I3, ClO4, or SO3CF3) have been synthesized and characterized. The electronic structures have been confirmed by using UV/Vis, IR, 1H NMR, EPR, and Mössbauer spectroscopy as well as signal-crystal X-ray diffraction studies. The neutral...
Paper Details
Title
Spin Modulation in Highly Distorted Fe III Porphyrinates by Using Axial Coordination and Their π‐Cation Radicals
Published Date
Jun 15, 2016
Volume
2016
Issue
21
Pages
3441 - 3453
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