Re-entry of tin in N-alkylation: first example of a homogeneous heterobimetallic Pd–Sn catalyst for base and additive free alkylation of amine and surrogates with alcohol
Abstract
The N-alkylation of amines, and amides with benzyl alcohols is catalyzed by bimetallic catalyst [Pd(COD)(SnCl3)Cl] in o-xylene. The reaction does not require additional base, additive or ligand, and is insensitive toward air and moisture and involves minimal work-up. These features make the reaction attractive, simple, and...
Paper Details
Title
Re-entry of tin in N-alkylation: first example of a homogeneous heterobimetallic Pd–Sn catalyst for base and additive free alkylation of amine and surrogates with alcohol
Published Date
Jun 1, 2016
Journal
Volume
57
Issue
25
Pages
2749 - 2753
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